A simple test to confirm the ligand substitution reactions of the hydrolytic iron(III) dimer

Authors
Lente, G Fabian, I
Citation
G. Lente et I. Fabian, A simple test to confirm the ligand substitution reactions of the hydrolytic iron(III) dimer, REACT KIN C, 73(1), 2001, pp. 117-125
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
73
Issue
1
Year of publication
2001
Pages
117 - 125
Database
ISI
SICI code
0133-1736(2001)73:1<117:ASTTCT>2.0.ZU;2-8
Abstract
Using a novel test method based on initial rates, periodate, dithionate, se lenite, phosphite, hypophosphite, and arsenate ions were confirmed to form transient multinuclear iron(III) complexes directly with the iron(III) hydr oxo dimer Fe-2(OH)(2)(H2O)(8)(4+).