Synthesis and study of ammonium hexamolybdenoindate(III)

Authors
Osminkina, IV Kaziev, GZ Kin'ones, SO de Ita, A
Citation
Iv. Osminkina et al., Synthesis and study of ammonium hexamolybdenoindate(III), RUSS J IN C, 46(7), 2001, pp. 959-961
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
7
Year of publication
2001
Pages
959 - 961
Database
ISI
SICI code
0036-0236(200107)46:7<959:SASOAH>2.0.ZU;2-K
Abstract
Ammonium hexamolybdenoindate(III) hydrate was synthesized and studied by IR spectroscopy and X-ray crystallography. The crystals of the compound are o rthorhombic with a = 11.034 Angstrom, b = 11.323 Angstrom, c = 5.903 Angstr om (+/-0.003 Angstrom), Z = 1, d(calc) = 3.125 g/cm(3). According to the mo lar conductivity of solutions and IR spectra, the compound is a poorly solu ble crystal hydrate with the coordination formula (NH4)(3)[InMoO6O18(OH)(6) ] . 10H(2)O. Its solubility in water was determined. Thermal stability of t he compound was studied by thermogravimetry.