The structures of the band gap and defect states of chemical-vapor-deposite
d diamond films were investigated by photoluminescence spectroscopy, coveri
ng wavelength from visible to vacuum ultraviolet (VUV). Band gaps ranging f
rom 5.5 to 3.2 eV were measured for natural, polycrystalline, and amorphous
diamond films. Low voltage field emissions were obtained from wide band ga
p films with band gap states distributed close to the conduction band and e
xtended deeply into the band gap. Amorphous diamond film with a narrower ba
nd gap could not provide low field emission. (C) 2001 Elsevier Science Ltd.
All rights reserved.