Conversion coatings modified by deposits of alumina, with or without zircon
ium, calcium, or strontium additions, have been studied as a way of improvi
ng the thermal oxidation resistance of a 17 Cr ferritic stainless steel. Co
nversion coatings, characterised by a particular morphology and strong inte
rfacial adhesion with the substrate, facilitate the electrochemical deposit
ion of ceramic layers and enhance their adhesion to the substrate. After he
ating, the coatings present a continuous composition gradient with refracto
ry compounds at the surface. The influence of added elements (Zr, Ca, or Sr
) on the behaviour of the alumina coating was investigated at 1000 degreesC
. Calcium improved the protective character of the alumina coating. The mor
phology and chemical composition of the different deposits were also analys
ed and results on the thermal stability of such coatings on Fe-17 Cr ferrit
ic stainless steel are presented.