Synthesis and properties of octakis(octylthio)porphyrazinatoiron derivatives

Authors
Hasanov, B Gul, A
Citation
B. Hasanov et A. Gul, Synthesis and properties of octakis(octylthio)porphyrazinatoiron derivatives, SYN REAC IN, 31(4), 2001, pp. 673-680
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
31
Issue
4
Year of publication
2001
Pages
673 - 680
Database
ISI
SICI code
0094-5714(200104)31:4<673:SAPOOD>2.0.ZU;2-W
Abstract
Chlorooetakis(octylthio)porphyrazinatoiron(III) (FePzCl) was prepared by th e reaction of metal-free porphyrazine with iron(II) acetate and further tre atment with HCl solution. The monomeric bisaxial complex FePz(PY)(2) as wel l as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting FePzCl with pyridine or pyrazine, respectively. These complexes we re characterized by elemental analysis and spectroscopic methods.