HAT(CN)(6): a new building block for molecule-based magnetic materials

Authors
Szalay, PS Galan-Mascaros, JR Clerac, R Dunbar, KR
Citation
Ps. Szalay et al., HAT(CN)(6): a new building block for molecule-based magnetic materials, SYNTH METAL, 122(3), 2001, pp. 535-542
Citations number
43
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
122
Issue
3
Year of publication
2001
Pages
535 - 542
Database
ISI
SICI code
0379-6779(20010801)122:3<535:HANBBF>2.0.ZU;2-Q
Abstract
The ability of reduced forms of HAT(CN)(6) to be used as ligands to constru ct novel magnetic materials is reported and discussed herein. Binary compou nds of first row transition metals with discrete or extended polymeric stru ctures are presented. Ail compounds exhibit characteristic paramagnetic beh aviour except for a polymeric {Cu-HAT(CN)(6)} phase that behaves as a cante d antiferromagnet below 6 K. (C) 2001 Elsevier Science B.V. All rights rese rved.