Enhanced trans diastereoselection in the allylation of cyclic chiral N-acyliminium ions. Synthesis of hydroxylated indolizidines

Authors
Klitzke, CF Pilli, RA
Citation
Cf. Klitzke et Ra. Pilli, Enhanced trans diastereoselection in the allylation of cyclic chiral N-acyliminium ions. Synthesis of hydroxylated indolizidines, TETRAHEDR L, 42(33), 2001, pp. 5605-5608
Citations number
27
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
33
Year of publication
2001
Pages
5605 - 5608
Database
ISI
SICI code
0040-4039(20010813)42:33<5605:ETDITA>2.0.ZU;2-7
Abstract
A short synthesis of hydroxylated indolizidines is reported. The key steps were the allylation of chiral cyclic N-acyliminium ions derived from malic and tartaric acids. followed by ring-closing metathesis. (C) 2001 Elsevier Science Ltd. All rights reserved.