Aminium hexachloroantimonate salts: a latent source of antimony pentachloride

Authors
Ciminale, F Lopez, L Farinola, GM Sportelli, S
Citation
F. Ciminale et al., Aminium hexachloroantimonate salts: a latent source of antimony pentachloride, TETRAHEDR L, 42(33), 2001, pp. 5685-5687
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
33
Year of publication
2001
Pages
5685 - 5687
Database
ISI
SICI code
0040-4039(20010813)42:33<5685:AHSALS>2.0.ZU;2-N
Abstract
Cyclization of an adamantylidene-based olefin induced by aminium hexachloro antimonate salts under a nitrogen atmosphere revealed that oxidative activa tion by these salts may be due to SbCl6, which in combination with an oxida nt counter-ion provides SbCl5 as the true reactive species. (C) 2001 Elsevi er Science Ltd. All rights reserved.