A thiolate-zinc complex with a Zn4O4 bicyclooctane framework

Authors
Schneider, A Vahrenkamp, H
Citation
A. Schneider et H. Vahrenkamp, A thiolate-zinc complex with a Zn4O4 bicyclooctane framework, Z ANORG A C, 627(8), 2001, pp. 1771-1774
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
8
Year of publication
2001
Pages
1771 - 1774
Database
ISI
SICI code
0044-2313(200108)627:8<1771:ATCWAZ>2.0.ZU;2-S
Abstract
The reaction of diethyl zinc with 2,4,6-triisopropyl thiophenol (HSR*) and N-methyl-2-hydroxymethyl imidazole (ImCH(2)OH) in methanol yields the compl ex Zn-4(SR*)(4) (ImCH(2)O)(3)(OMe) with terminal SR* and bridging ImCH(2)O and MeO ligands. The structure of its Zn4O4 framework is that of a bicyclo [2.2.2] octane with Zn and O at the two apices.