Structure and electrochemical study of Nb3Cl8

Authors
Strobele, M Glaser, J Lachgar, A Meyer, HJ
Citation
M. Strobele et al., Structure and electrochemical study of Nb3Cl8, Z ANORG A C, 627(8), 2001, pp. 2002-2004
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
8
Year of publication
2001
Pages
2002 - 2004
Database
ISI
SICI code
0044-2313(200108)627:8<2002:SAESON>2.0.ZU;2-C
Abstract
The compound Nb3Cl8 was synthesized from NbCl5 and niobium metal in a seale d quartz ampoule at 700 degreesC, Single crystals, obtained from LiCl melt were used for X-ray structure determination (space group P3 m1, Z = 2. latt ice parameters a = b = 672.95(7) pm, c = 1223.2(2) pm (at 100 K), R1 = 0.02 9, wR2 = 0.064 for all independent reflections). Electrical resistivity mea surements are reported. Electrochemical intercalation of lithium into the s tructure of Nb3Cl8 was studied.