The syntheses of symmetric ureas by oxidative carbonylation of amines overresin immobilized gold

Authors
Shi, F Deng, YQ Gong, CK Sima, TL Yang, HZ
Citation
F. Shi et al., The syntheses of symmetric ureas by oxidative carbonylation of amines overresin immobilized gold, ACT CHIM S, 59(8), 2001, pp. 1330-1334
Citations number
19
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
59
Issue
8
Year of publication
2001
Pages
1330 - 1334
Database
ISI
SICI code
0567-7351(2001)59:8<1330:TSOSUB>2.0.ZU;2-H
Abstract
Symmetric ureas were synthesized with high efficiency and selectivity by ox idative carbonylation of aromatic and aliphatic amines in the presence of r esin immobilized gold, e.g. 1475 of TOF and 99% of selectivity were achieve d when using aniline as the substrate. No other organic solvent was used in the reactions and highly pure products could be obtained due to the high s electivity and the easy separation of the catalyst from the reaction system .