We show that a morphological instability driven by deviatoric applied stres
ses can generate elastically induced particle splitting during diffusional
phase transformations. The splitting instability occurs when the elastic fi
elds are above some critical value. For subcritical elastic fields, one obs
erves a small perturbation of the particle shape consistent with splitting,
but this perturbation is stabilized by surface tension. Both the onset of
the splitting instability and the nonlinear evolution of the particle towar
ds splitting depend on the precise form of the applied stress, the elastic
constants of the precipitate and matrix, and the initial shape of the preci
pitate. We also investigate whether non-dilatational misfit strains can gen
erate splitting instabilities in the absence of an applied stress. (C) 2001
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ed.