The ability to control the nanoscale shape of nanostructures in a large-sca
le synthesis process is an essential and elusive goal of nanotechnology res
earch. Here, we report significant progress toward that goal. We have devel
oped a technique that enables controlled synthesis of nanoscale carbon stru
ctures with conical and cylinder-on-cone shapes and provides the capability
to dynamically change the nanostructure shape during the synthesis process
. In addition, we present a phenomenological model that explains the format
ion of these nanostructures and provides insight into methods for precisely
engineering their shape. Since the growth process we report is highly dete
rministic in allowing large-scale synthesis of precisely engineered nanosca
le components at defined locations, our approach provides an important tool
for a practical nanotechnology. (C) 2001 American Institute of Physics.