Yb. Xie et Tn. Ruan, Independent N-electron method and high accuracy calculations of the groundstate energy of the nonrelativistic light atoms (3 <= N-e <= 10), COMM TH PHY, 36(1), 2001, pp. 79-84
A new method based on the independent electron-pair approximation is develo
ped to calculate the correlation energy and the basis size truncation error
. The formalisms for the nondegenerate systems are described in this paper.
Because all important terms are very efficiently selected and the calculat
ions can be separated into several parts, this new method gives very accura
te results and does not require expensive computing facilities. As a test,
the ground state energies (GSE) of the nonrelativistic atoms for 3 less tha
n or equal to N-e less than or equal to 10 are calculated using this new me
thod. The calculated results are found to be in close agreement with the mo
st recent available version of the exact GSE which is derived from the expe
rimental data after subtracting the contributions from the relativistic eff
ect, QED radiative corrections, finite nucleon mass corrections, and the fi
nite radius of the nuclear size. Those accurate results have not been repro
duced for N-e greater than or equal to 5 by any direct theoretical calculat
ions in literatures. Since this method is not restrained to nonrelativistic
or Coulomb systems, it should become powerful to study other quantum inter
acting systems.