A union of the real-space and reciprocal space view of the GaAs(001) surfac
e is presented. An optical transmission temperature measurement system allo
wed fast and accurate temperature determinations of the GaAs(001) substrate
. The atomic features of the GaAs(001)-(2 x 4) reconstructed surface are re
solved with scanning tunneling microscopy and first principles density func
tional theory. In addition, the 2D lattice-gas Ising model within the grand
canonical ensemble can be applied to this surface to understand the thermo
dynamics. An algorithm for using electron diffraction on the GaAs(001) surf
ace to determine the substrate temperature and tune the nanoscale surface r
oughness is presented.