A GaAs/AlGaAs structure coated with molecules was investigated utilizing mi
crowave modulated photoluminescence (MMPL) spectroscopy. This method enable
d to resolve the photoluminescence (PL) band into localized and de-localize
d excitons. The results indicated a limited in-plan mobility of the exciton
s, due to electrostatic fluctuations or band bending induced by the adsorbe
d molecules. The reduction of exciton mobility is correlated with the reduc
tion in the photocurrent observed in former studies. The present study prov
ides an insight into the mechanism which couples molecules with a semicondu
ctor structure and explains its operation as a molecular controlled semicon
ductor resistor (MOCSER), found to be a sensitive actuator in sensor applic
ations. (C) 2001 American Institute of Physics.