We study spin-dependent electronic transport across ferromagnet/superconduc
tor ballistic junctions modeled using tight-binding Hamiltonians with s, p
and d orbitals and material-specific parameters. The first result of this p
aper is that, by accurately modeling the band structure of the bulk materia
ls, one can reproduce the measured differential conductance of Cu/Pb nanoco
ntacts(1,2). In contrast the differential conductance of Co/Pb contacts can
only be reproduced if an enhanced magnetic moment is present at the interf
ace. The second result concerns the reliability of a method proposed in Ref
s. 1-3 for determining the degree of polarization of a ferromagnet. By fitt
ing the material-specific differential conductance curves to curves calcula
ted using a single-band model we show that this method does not yield relia
ble values for polarization and spin-dependent transmission.