In situ straining experiments in a transmission electron microscope have be
en carried out on a Ti3Al intermetallic alloy, with the aim of determining
the microscopic mechanisms controlling glide in prism, basal and pyramidal
planes. Five different antiphase boundary energies have been measured and c
ompared with the corresponding densities of incorrect first nearest neighbo
ur atoms. The determination of a tension-compression asymmetry in pyramidal
slip, and the detailed analysis of the complex microscopic mechanisms invo
lved illustrate the efficiency of in situ experiments to solve complex prob
lems in plasticity. A comparison between the properties of the different sl
ip systems shows that they are controlled by different microscopic mechanis
ms, none of them being of covalent origin.