The characteristic behaviors of CH3Br are examined first for the dry etchin
g of polysilicon in a Cl-2/CH3Br/O-2 plasma. CH3Br is revealed as one of th
e excellent additive gases to control anisotropy of the etching profile and
to give no undercutting for various types of polysilicons. The fragments f
rom CH3Br plasma would act as passivation precursors on the sidewalls in et
ch cavity. The decrease of etch selectivity due to the reaction of the C-co
ntaining species front CH3Br with the surface O atoms of SiO2 is overcome b
y the addition of O-2 into the plasma. (C) 2001 The Electrochemical Society
. [DOI: 10.1149/1.1383555] All rights reserved.