Proton dynamics in isomorphous TIH2PO4 and TIH2AsO4

Citation
Kw. Lee et al., Proton dynamics in isomorphous TIH2PO4 and TIH2AsO4, J KOR PHYS, 39(2), 2001, pp. 394-397
Citations number
18
Categorie Soggetti
Physics
Journal title
JOURNAL OF THE KOREAN PHYSICAL SOCIETY
ISSN journal
03744884 → ACNP
Volume
39
Issue
2
Year of publication
2001
Pages
394 - 397
Database
ISI
SICI code
0374-4884(200108)39:2<394:PDIITA>2.0.ZU;2-7
Abstract
The proton dynamics in TlH2PO4 (TDP) and TlH2AsO4 (TDA) was studied by mean s of H-1 nuclear magnetic resonance. In spite of their very similar crystal structures and phase transition sequences, these two isomorphous ferroelec trics showed distinct behaviors in proton motions through the ferroelastic phase transition temperature. Our results may be understood in terms of the coupled hydrogen-lattice model and are associated with distortion of the P O4 (-)/AsO4- tetrahedra.