Titanium species in titanium silicalite TS-1 prepared by hydrothermal method

The titanium species existing in titanium silicalite TS-1, which is prepare d by hydrothermal method, were investigated using chemical analysis, XRD, F T-IR, Si-29 MAS NMR, UV-VIS, ESR. It has been observed that several kinds o f titanium species may exist in titanium silicalite. The form that titanium atoms incorporate into the framework of titanium silicalite synthesized us ing tetrapropylammonium bromide (TPABr) as template differs from that using the classical method. But, the symmetry of titanium silicalite, changes fr om monoclinic to orthorhombic with the increase of titanium content in both methods. The Ti-O-2(-) originated from framework titanium and H2O2 has the moderate stability and may be active site in oxidation reaction. TS-1 synt hesized using TPABr as template does not contain anatase, but contains a ki nd of partly condensed titanium species with six-fold coordination. The tit anium species may correspond to 270-280 mn band in UV-VIS spectra and also can form Ti-O-2(-). But, this kind of Ti-O-2(-) is very stable and cannot b e catalytic active site. So, the six-fold coordination titanium species may be inactive in both the oxidation reaction and the decomposition of H2O2. The hypothesis has been further proved by the phenomena that the titanium s pecies is easily washed off using acid, and acid treating will not influenc e the catalytic performance of TS-1. (C) 2001 Elsevier Science B.V. All rig hts reserved.