Formation of novel 1 : 1 adducts accompanied by regioselective hydride transfer from transition-metal hydrido complexes to NAD(P) models

Authors
Kobayashi, A Takatori, R Kikuchi, I Konno, H Sakamoto, K Ishitani, O
Citation
A. Kobayashi et al., Formation of novel 1 : 1 adducts accompanied by regioselective hydride transfer from transition-metal hydrido complexes to NAD(P) models, ORGANOMETAL, 20(16), 2001, pp. 3361-3363
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
16
Year of publication
2001
Pages
3361 - 3363
Database
ISI
SICI code
0276-7333(20010806)20:16<3361:FON1:1>2.0.ZU;2-0
Abstract
Important intermediates in regioselective hydride reduction of NAD(P) model compounds were detected by various spectroscopic methods. The metal hydrid o complexes [Ru(tpy)(bpy)H](+) and [Re(bpy)-(CO)(3)H] react with the NAD(P) models to give 1:1 adducts, which are cleaved to the 1,4-dihydro form of t he models and the solvento complexes, quantitatively.