Main-group-metal chlorobenzene complexes

Authors
Korolev, AV Delpech, F Dagorne, S Guzei, IA Jordan, RF
Citation
Av. Korolev et al., Main-group-metal chlorobenzene complexes, ORGANOMETAL, 20(16), 2001, pp. 3367-3369
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
16
Year of publication
2001
Pages
3367 - 3369
Database
ISI
SICI code
0276-7333(20010806)20:16<3367:MCC>2.0.ZU;2-6
Abstract
Stable group 13 metal chlorobenzene complexes of general type [(Pr-i(2)-ATI )MR][B(C6F5)(4)](ClPh) (M = Al, Ga, In; Pr-i(2)-ATI = N,N ' -diisopropylami notroponiminate) have been isolated. X-ray crystallographic studies show th at the PhCl ligands in these compounds are coordinated by dative M-ClPh bon ding and suggest that pi -stacking interactions between the PhCl phenyl rin g and the iPr2-ATI ligand may also contribute to the PhCl coordination.