Four sulfated steroid compounds were isolated from the Kuril population of
the starfish Aphelasterias japonica. The structure of a new glycoside, aphe
lasteroside D, was elucidated as (24R)-29-O-[2-O-sulfo-beta -D-glucopyranos
yl]-24-ethyl-5 alpha -cholestane-3 beta ,5,6 beta ,8 beta ,15 alpha ,29-hex
ol sodium salt. Other three substances were identified as the known pycnopo
dioside C, 3-O-sulfo-24,25-dihydromarthasterone, and 3-O-sulfothornasterol
A, the latter compound being isolated as a tyrammonium salt for the first t
ime.