Complex of tetrachlorogermane with dimethyl sulfoxide and its IR spectral study

Authors
Voronkov, MG Gavrilova, GA Basenko, SV
Citation
Mg. Voronkov et al., Complex of tetrachlorogermane with dimethyl sulfoxide and its IR spectral study, RUSS J G CH, 71(2), 2001, pp. 210-212
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
2
Year of publication
2001
Pages
210 - 212
Database
ISI
SICI code
1070-3632(200102)71:2<210:COTWDS>2.0.ZU;2-I
Abstract
The complex 2(Me2SO)_GeCl4 in which the hexacoordinate germanium atom is co ordinated via oxygen atoms with two Me2S=O molecules was studied by IR spec troscopy. The strong doublet band with maxima at 495 and 506 cm(-1) in the spectrum of the complex was assigned to stretching vibrations of the Ge-O c oordination bond. Thermolysis of 2(Me2SO) . GeCl4 yields, along with the co nsituent molecules, polyoxymethylene, dimethyl disulfide, and trace amounts of chloromethyl methyl sulfide.