Complex formation of potassium hexachloroplatinate with 18-crown-6 and dibenzo-18-crown-6 in acetonitrile

Authors
Guseva, EV Busygina, TE Gracheva, LS Polovnyak, VK Khasanshin, RA Yarkova, EG Yusupov, RA
Citation
Ev. Guseva et al., Complex formation of potassium hexachloroplatinate with 18-crown-6 and dibenzo-18-crown-6 in acetonitrile, RUSS J G CH, 71(2), 2001, pp. 217-221
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
2
Year of publication
2001
Pages
217 - 221
Database
ISI
SICI code
1070-3632(200102)71:2<217:CFOPHW>2.0.ZU;2-B
Abstract
The products of the reactions between potassium hexachloroplatinate {K2PtCl 6} and 18-crown-6 or dibenzo-18-crown-6 in acetonitrile were studied. Pure crystalline compounds [2K(.)2(18-crown-6). 2CH(3)CN](2+.)[PtCl6](2-.)2H(2)O , [2K(.)dibenzo-18-crown-6(.)CH(3)CN](2+.)[PtCl6](2-), and [2K(.)dibenzo-18 -crown-6 (CH3CN)-C-.](2+.)[Pt2Cl10](2-) were obtained. Physicochemical prop erties of these compounds were studied, and their near- and far-IR IR spect ra and thermogravimetric curves were considered. The composition of the com plexes is determined by metal: ligand molar ratio and crown ether nature. I t was found that acetonitrile is coordinated via the nitrogen atom.