Synthesis and reactions of ethynyl derivatives of adamantanone, verbanone,and verbenone

Authors
Dikusar, EA Kozlov, NG Koval'skaya, SS Popova, LA Moiseichuk, KL
Citation
Ea. Dikusar et al., Synthesis and reactions of ethynyl derivatives of adamantanone, verbanone,and verbenone, RUSS J G CH, 71(2), 2001, pp. 290-293
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
2
Year of publication
2001
Pages
290 - 293
Database
ISI
SICI code
1070-3632(200102)71:2<290:SAROED>2.0.ZU;2-G
Abstract
Lithium acetylide was reacted with adamantanone, verbanone, and verbenone t o obtain their hydroxyethynyl derivatives whose reaction with aqueous ammon ia solution of silver nitrate gave the corresponding polycycloaliphatic sil ver acetylides. The latter react with iodine, yielding hydroxyethynyl iodid es. Acetates of the adamantane-containing ethynyl alcohols were prepared.