Thermochemistry of solution of Fe(III) and Mn(III) complexes with natural porphyrins

Authors
Berezin, MB
Citation
Mb. Berezin, Thermochemistry of solution of Fe(III) and Mn(III) complexes with natural porphyrins, RUSS J G CH, 71(2), 2001, pp. 294-298
Citations number
22
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
2
Year of publication
2001
Pages
294 - 298
Database
ISI
SICI code
1070-3632(200102)71:2<294:TOSOFA>2.0.ZU;2-D
Abstract
The enthalpies of solution of Fe(III) and Mn(III) complexes with porphyrins of the chlorophyll group (chlorophyll ligand, pheophorbid, chlorin e(6)) a nd protoporphyrin in various organic solvents at 298.15 K were determined c alorimetrically. The influence of the structural features of porphyrin mole cules and nature of the solvent on the enthalpy characteristics of porphyri n-sol vent interaction was discussed.