Solid solutions of europium(III) and gadolinium(III) trifluoroacetate trihydrates as precursors of solid solutions of europium and gadolinium trifluorides

Authors
Sokolova, NP Lisoivan, VI Varand, VL Larionov, SV
Citation
Np. Sokolova et al., Solid solutions of europium(III) and gadolinium(III) trifluoroacetate trihydrates as precursors of solid solutions of europium and gadolinium trifluorides, RUSS J G CH, 71(1), 2001, pp. 15-18
Citations number
4
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
1
Year of publication
2001
Pages
15 - 18
Database
ISI
SICI code
1070-3632(200101)71:1<15:SSOEAG>2.0.ZU;2-3
Abstract
The system Eu(CF3CO2)(3)-Gd(CF3CO2)(3)-H2O, which forms solid solutions Eux Gd1-x(CF3CO2)(3). 3H(2)O, was studied. The thermolysis of these solutions a t 350-360 degreesC yields solid solutions of lanthanide trifluorides. X-ray examination showed that these solid solutions are formed on the basis of t he predominantly rhombic phase of Eu(III) and Gd(III) trifluorides.