Thermal stability of mono- and polycyclic peroxyalcohols and their derivatives by thermal analysis

Authors
Yuvchenko, AP Dikusar, EA Kozlov, NG Zelenkovskii, VM Prokopchuk, NR Filanchuk, LP Moiseichuk, KL
Citation
Ap. Yuvchenko et al., Thermal stability of mono- and polycyclic peroxyalcohols and their derivatives by thermal analysis, RUSS J G CH, 71(1), 2001, pp. 102-108
Citations number
13
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
1
Year of publication
2001
Pages
102 - 108
Database
ISI
SICI code
1070-3632(200101)71:1<102:TSOMAP>2.0.ZU;2-5
Abstract
A comparative study of the thermal stability of 33 mono- and polycyclic per oxyalcohols, as well as ethers and esters derived from them was performed b y thermal analysis. Reaction orders and apparent rate constants of the firs t stage of peroxide decomposition were determined from the DTA curves. Semi empirical quantum-chemical calculations of the strength of the O-O bond in peroxycycloalkanols and peroxyalcohols of the adamantane series and their d erived esters were performed.