Ap. Yuvchenko et al., Thermal stability of mono- and polycyclic peroxyalcohols and their derivatives by thermal analysis, RUSS J G CH, 71(1), 2001, pp. 102-108
A comparative study of the thermal stability of 33 mono- and polycyclic per
oxyalcohols, as well as ethers and esters derived from them was performed b
y thermal analysis. Reaction orders and apparent rate constants of the firs
t stage of peroxide decomposition were determined from the DTA curves. Semi
empirical quantum-chemical calculations of the strength of the O-O bond in
peroxycycloalkanols and peroxyalcohols of the adamantane series and their d
erived esters were performed.