Kinetics of 1,3-cycloaddition of alpha-diazoalkanones to maleic anhydride

Authors
Rodina, LL Karavaeva, SA Nikolaev, VV Dubitskii, VV
Citation
Ll. Rodina et al., Kinetics of 1,3-cycloaddition of alpha-diazoalkanones to maleic anhydride, RUSS J ORG, 37(2), 2001, pp. 214-216
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
2
Year of publication
2001
Pages
214 - 216
Database
ISI
SICI code
1070-4280(200102)37:2<214:KO1OAT>2.0.ZU;2-F
Abstract
The kinetics of 1,3-cycloaddition to maleic anhydride were studied by examp les of reaction with five-, six-, and seven-membered alpha -diazocycloalkan ones. The order of magnitude of the thermodynamic activation parameters in the reaction series investigated corresponds to a concerted mechanism of th e process under consideration.