Ozonolysis of alkenes and study of reactions of polyfunctional compounds: LXIV. Synthesis of ambreinolide and 8 alpha,13-epoxy-14,15,16-trisnorlabd-12-ene proceeding from isoabienol ozonolysis
Os. Kukovinets et al., Ozonolysis of alkenes and study of reactions of polyfunctional compounds: LXIV. Synthesis of ambreinolide and 8 alpha,13-epoxy-14,15,16-trisnorlabd-12-ene proceeding from isoabienol ozonolysis, RUSS J ORG, 37(2), 2001, pp. 235-237
The ozonolysis of isoabienol in MeOH followed by hydrogenation of the perox
ide ozonolysis products on Lindlar catalyst afforded ambreinolide that unde
r treatment with diisobutylaluminum hydride furnished 8 alpha ,13-epoxy-14,
15,16-trisnorlabd-12-ene.