Ozonolysis of alkenes and study of reactions of polyfunctional compounds: LXIV. Synthesis of ambreinolide and 8 alpha,13-epoxy-14,15,16-trisnorlabd-12-ene proceeding from isoabienol ozonolysis

Authors
Kukovinets, OS Zainullin, RA Odinokov, VN Kislitsyn, MI Roshchin, VI Galin, FZ Tolstikov, GA
Citation
Os. Kukovinets et al., Ozonolysis of alkenes and study of reactions of polyfunctional compounds: LXIV. Synthesis of ambreinolide and 8 alpha,13-epoxy-14,15,16-trisnorlabd-12-ene proceeding from isoabienol ozonolysis, RUSS J ORG, 37(2), 2001, pp. 235-237
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
2
Year of publication
2001
Pages
235 - 237
Database
ISI
SICI code
1070-4280(200102)37:2<235:OOAASO>2.0.ZU;2-Y
Abstract
The ozonolysis of isoabienol in MeOH followed by hydrogenation of the perox ide ozonolysis products on Lindlar catalyst afforded ambreinolide that unde r treatment with diisobutylaluminum hydride furnished 8 alpha ,13-epoxy-14, 15,16-trisnorlabd-12-ene.