Synthesis and cyclization of diketones from the adamantane series

Authors
Makarova, NV Moiseev, IK Zemtsova, MN
Citation
Nv. Makarova et al., Synthesis and cyclization of diketones from the adamantane series, RUSS J ORG, 37(2), 2001, pp. 256-259
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
2
Year of publication
2001
Pages
256 - 259
Database
ISI
SICI code
1070-4280(200102)37:2<256:SACODF>2.0.ZU;2-Q
Abstract
Cyclic beta- and gamma -diketones of the adamantane series were synthesized by reactions of chlorides of 1-adamantanecarboxylic acids and 1-adamantyl bromomethyl ketone with cyclic enamines 1-morpholino-1-cyclopentene and 1-m orpholino-1-cyclohexene. Cyclization of the beta -diketones obtained was pe rformed by reaction with hydroxylamine and phenylhydrazine.