Synthesis of alpha,beta-epoxy ketones from alkyl- and arylsubstituted cyclopropanols

Authors
Kulinkovich, OG Astashko, DA Tyvorskii, VI Ilyina, NA
Citation
Og. Kulinkovich et al., Synthesis of alpha,beta-epoxy ketones from alkyl- and arylsubstituted cyclopropanols, SYNTHESIS-S, (10), 2001, pp. 1453-1455
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
10
Year of publication
2001
Pages
1453 - 1455
Database
ISI
SICI code
0039-7881(200108):10<1453:SOAKFA>2.0.ZU;2-5
Abstract
A number of aliphatic and arylaliphatic alpha,beta -epoxy ketones were prep ared in good yields in a one-pot procedure by a manganese-catalyzed ring cl eavage of I-substituted and 1,2-disubstituted cyclopropanols with oxygen fo llowed by dehydration of the resulting cyclic peroxides with alkali.