Macrocrystalline colloidal assemblies with tunable non-spherical shape are
fabricated through colloidal crystallization under an AC electric field. Al
so, by field-induced drop breakup, uniform micrometer-sized macrocrystallin
e particles can be synthesized (see Figure). Interestingly, the electrical
field promotes infiltration of the suspending oil, which can be used for fa
bricating photonic crystals with high refractive index mismatch.