Thick GaN layers were sown by hydride vapor phase epitaxy (HVPE) with
the aim of using these layers as a homoepitaxial substrate to improve
device quality of laser diodes or light emitting diodes. HVPE is very
useful for thick layer growth since the growth rate can reach from sev
eral ten up to one hundred micron per hour, In this experiment, the gr
owth began as selective growth through openings formed in a SiO2 mask.
Facets consisting of {1 (1) over bar 01} planes were formed in the ea
rly stage and a continuous film developed from the coalescence of thes
e facets on the SiO2 mask. As a result, GaN layers with a dislocation
density as low as 6 x 10(7) cm(-2) were grown on 2-inch-diameter sapph
ire wafers. These GaN layers were crack-free and had mirror-like surfa
ce.