SURFACE CHARACTERIZATION AND CORROSION BEHAVIOR OF SIC-COATED AISI-321 STAINLESS-STEEL

The influence of SiC-coatings on the corrosion properties of AISI 321 austenitic stainless steel (Fe/Cr18/Ni8/Ti) in 1N H2SO4 was studied. S iC-coatings of various thicknesses (100-800 nm) were prepared at room temperature (RT) or at temperatures up to 750 degrees C by ion beam sp uttering of a SiC-target. The growing films could be continuously bomb arded with a 160 keV Ar+ ion beam and the role of this Dynamic Ion Mix ing (DIM) on both the structure and corrosion resistance was investiga ted. The chemical composition of the coatings was determined by Ruther ford Backscattering (RBS) using 1.8 MeV alpha-particles and by Nuclear Reaction Analysis (NRA). Transmission Electron Microscopy (TEM) obser vations were also performed for the determination of the microstructur al state of the samples. The characterisation shows, that for all the deposition temperatures the DIM-treatment promotes the crystallisation of the beta-SiC phase. It was also found, that the corrosion resistan ce of the stainless steel is considerably improved when the coatings a re deposited by DIM regardless of the deposition temperature. The poss ible mechanisms are discussed and it is suggested that the interface m ixing along with the coating densification effect are responsible for the improvement of the corrosion resistance.