D. Doppalapudi et Sn. Basu, STRUCTURE OF MULLITE COATINGS GROWN BY CHEMICAL-VAPOR-DEPOSITION, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 231(1-2), 1997, pp. 48-54
Dense mullite coatings have been deposited on SiC and Si3N4 substrates
by chemical vapor deposition (CVD). The coatings were compositionally
graded with the Al/Si ratio increasing from 1.5 at the substrate/coat
ing interface, to a value of 8 at the coating surface. This gradation
of composition is discussed in light of changes in the concentration o
f oxygen vacancies, ordering of the vacancies, formation and size of d
omains and the observed changes in lattice parameters. (C) 1997 Elsevi
er Science S.A.