Nanostructured WC Co coatings were prepared with the vacuum plasma spraying
process. The microstructure of the as-prepared coatings was determined wit
h SEM, TEM and XRD. The results show that the main structure of the coating
s is composed of WC grains with a mean particle size of 35 nm, which have a
similar grain size to the primary powders. However, in some regions, the g
rain size of WC is reduced to about 10 nm due to the melting of the WC-Co p
owders. In some regions, WC grains are completely melted forming an amorpho
us phase. In some regions, WC grains have grown to 100 nm; in other regions
, the second recrystallization occurred, strip-shaped and square-shaped str
uctures are formed, which are as large as 500 nm. The main phase of the as-
preparcd WC Co coating is WC with minor phases of alpha -W2C, beta -WC1-x,
and W3Co3C. The hardness of the coating is about 18 Gpa with a wide distrib
ution. (C) 2001 Published by Elsevier Science Ltd and Techna S.r.l. All rig
hts reserved.