Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters

Authors
Pugh, RI Drent, E Pringle, PG
Citation
Ri. Pugh et al., Tandem isomerisation-carbonylation catalysis: highly active palladium(II) catalysts for the selective methoxycarbonylation of internal alkenes to linear esters, CHEM COMMUN, (16), 2001, pp. 1476-1477
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
16
Year of publication
2001
Pages
1476 - 1477
Database
ISI
SICI code
1359-7345(20010821):16<1476:TICHAP>2.0.ZU;2-W
Abstract
Fast, selective conversion of internal olefins to linear esters is catalyse d by Pd(II) complexes of chelating bis(phosphaadamantyl)diphosphines and th e catalysis is acutely sensitive to the ligand backbone and even to the dia stereomer used; the results are compared with those for the PBU2t analogue.