B. Yao et al., Determination of cadmium at ultra-trace level by FI cold vapor generation AAS with on-line ion exchange preconcentration, CHEM J CH U, 22(8), 2001, pp. 1301-1304
A method for the determination of cadmium by flow injection cold vapor gene
ration atomic absorption spectrometry (FI-CVGAAS) with an on-line ion excha
nge micro-column preconcentration system was developed using IRC-718, 122 a
nd Muromac A-1 resin. The interferences from coexisting elements were studi
ed. The detection limit(3 sigma) was 2. 3-3. 0 ng/L with a sampling frequen
cy of 45-60/h. The precision was 2. 0%-2-6% RSD(n = 11) at 0. 2 mug/L level
. The method was applied to the analysis of water samples. Satisfactory rec
overies of cadmium in reservoir water, tap water and brine waters were obta
ined for spiked samples.