Preparation of LLDPE with dual-functional catalytic system Ti(OBu-n)(4)/AlEt3-[Me(2)SiN(t)BuInd]ZrCl2/MAO

Authors
Liu, ZY Wang, J Li, XH He, DW Hu, YL Yan, WD
Citation
Zy. Liu et al., Preparation of LLDPE with dual-functional catalytic system Ti(OBu-n)(4)/AlEt3-[Me(2)SiN(t)BuInd]ZrCl2/MAO, CHEM J CH U, 22(7), 2001, pp. 1271-1273
Citations number
8
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
22
Issue
7
Year of publication
2001
Pages
1271 - 1273
Database
ISI
SICI code
0251-0790(200107)22:7<1271:POLWDC>2.0.ZU;2-F
Abstract
This paper reports a new kind catalytic system to produce linear low densit y polyethylene (LLDPE) from ethylene alone in a single reactor by combining the ability of Ti(OBu-n)(4)/AlEt3 to produce 1-butene with the ability of [Me(2)SiN(t)BuInd]ZrCl2/MAO to copolymerize ethylene with 1-butene. It was found that the dual-functional catalytic system has high activity and get t he good polymer with density ranging from 0.91-0.95 g/cm(3) in ethylene pol ymerization.