ZnO crystal whiskers were prepared via a simple thermal evaporation of a mi
xture of ZnS and Fe(NO3)(3). The growth process was carried out in an alumi
na tube at 1300 degreesC using Ar mixed with 5% H-2 as the carrier gas. The
ZnO whiskers obtained had diameters ranging from 200 to 500 urn and length
s up to several hundreds of micrometers. The photoluminescence spectrum of
as-grown ZnO whiskers was studied. The influences of reaction temperature,
time, and carrier gases on the formation of the whiskers were investigated.
A preliminary growth mechanism of the ZnO crystal whiskers was proposed. (
C) 2001 Elsevier Science B.V. All rights reserved.