Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands

Authors
Ohta, H Harada, K Irie, K Kashino, S Kambe, T Sakane, G Shibahara, T Takamizawa, S Mori, W Nonoyama, M Hirotsu, M Kojima, M
Citation
H. Ohta et al., Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands, CHEM LETT, (8), 2001, pp. 842-843
Citations number
4
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
8
Year of publication
2001
Pages
842 - 843
Database
ISI
SICI code
0366-7022(20010805):8<842:DATNCC>2.0.ZU;2-#
Abstract
The reaction of Nil, with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N -salicylideneaminomethyl)ethane) afforded the O-H . . .O bridged dinuclear [Ni-2(HL)(2)] complex. When Ni2+ was allowed to react with H3L in the prese nce of triethylamine (3 : 2 : 6), the linear trinuclear [Ni-3(L)(2)] comple x formed, where the central nickel(II) ion is bridged by six phenolate oxyg en atoms to the terminal nickel(II) ions.