Semisynthesis of cis- and trans-solamin by acidic opening of natural diepomuricanin A - a mechanistic investigation

Authors
Gleye, C Franck, X Hocquemiller, R Laurens, A Laprevote, O de Barros, S Figadere, B
Citation
C. Gleye et al., Semisynthesis of cis- and trans-solamin by acidic opening of natural diepomuricanin A - a mechanistic investigation, EUR J ORG C, (16), 2001, pp. 3161-3164
Citations number
24
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
16
Year of publication
2001
Pages
3161 - 3164
Database
ISI
SICI code
1434-193X(200108):16<3161:SOCATB>2.0.ZU;2-X
Abstract
MS/MS spectroscopy allowed us to determine the mechanism of the acidic open ing of diepomuricanin A, by analysis of the product distribution after trea tment with (H2O)-O-18 in the presence of HClO4 in anhydrous acetone.