One-dimensional chain crown ether complex - Synthesis and crystal structure of novel complex: {[Na(18C6)][Na(18C6)(H2O)]}[Cu(mnt)(2)]

Authors
Dou, JM Li, DC Sun, DZ Liu, Y Xu, LQ Bi, WH Zheng, PJ
Citation
Jm. Dou et al., One-dimensional chain crown ether complex - Synthesis and crystal structure of novel complex: {[Na(18C6)][Na(18C6)(H2O)]}[Cu(mnt)(2)], I J CHEM A, 40(8), 2001, pp. 878-879
Citations number
15
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
8
Year of publication
2001
Pages
878 - 879
Database
ISI
SICI code
0376-4710(200108)40:8<878:OCCEC->2.0.ZU;2-M
Abstract
The reaction of 18-crown-6 with Na2Cu(mnt)(2) (mnt = 1,2-dicyanoethene-1,2- dithiolate, C2S2(CN)(2)(2-)) gives the novel complex, ([Na(18C6)][Na(18C6)( H2O)]}[Cu(mnt)(2)]. The complex has been characterized by elemental analysi s, IR spectrum and X-ray diffraction analysis. The complex displays a one-d imensional infinite chain of [Na(18C6)](+) complex cations and [Cu(mnt)(2)] (2-) complex anion bridged by Na-N interactions between adjacent [Na(18C6)] (+) units.