Reactivity studies of [Ru(L-L)(2)Cl-2] (L-L=2,2 '-bipyridine or 1,10-phenanthroline) with AgNO3 in different media

Authors
Malhotra, A Poddar, RK
Citation
A. Malhotra et Rk. Poddar, Reactivity studies of [Ru(L-L)(2)Cl-2] (L-L=2,2 '-bipyridine or 1,10-phenanthroline) with AgNO3 in different media, I J CHEM A, 40(8), 2001, pp. 883-886
Citations number
13
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
8
Year of publication
2001
Pages
883 - 886
Database
ISI
SICI code
0376-4710(200108)40:8<883:RSO[('>2.0.ZU;2-D
Abstract
Reactions of [Ru(L-L)(2)] (L-L = 2,2 ' -bipyridine or 1,10-phenanthroline) with AgNO3 have been carried out in ethanol, acetonitrile acetone, and 2-et hoxy ethanol media and compounds of the type [Ru(L-L)(2)(H2O)(NO3)](NO3), [ Ru(L-L)(2)(CH3CN)(2)](ClO4)(2) and [Ru(CO)(2)(bipy)(2)](ClO4)(2) are obtain ed. A reaction of [Ru(L-L)(2)(H2O)(NO3)](NO3) with HClO4 result in the form ation of [Ru(L-L)(2)(NO)(NO3)](ClO4)(2). All the compounds have been charac terised by analytical data, conductivity measurements, IR, UV-visible and c yclic voltametric studies. Formation of different compounds in different so lvents have also been rationalised.