The vulcanization of asphalt/styrene-butadiene-styrene (SBS) triblock copol
ymer blends in the presence of elemental sulfur was followed with a strain-
controlled rheometer. The vulcanization of the blends took place at tempera
tures greater than 140 degreesC. From 150 to 180 degreesC, the curing rate
of the blends increased significantly with increasing temperature, and the
apparent activation energy of vulcanization was 45.2 kJ mol(-1). A suitable
processing temperature for good mechanical and thermally stable properties
was between 170 and 180 degreesC. Both the structure of SBS and the sulfur
level had important effects on the vulcanization of the blends. A plot of
the electric current versus time showed the process of the dynamic vulcaniz
ation of the blends. (C) 2001 John Wiley & Sons, Inc.