Redetermination of the structure of bis[chloro-2-(2-hydroxy-4,5-dimethylphenylazo)-5, 5-dimethyl-4,5,6,7-tetrahydrobenzothiazol-7-on] copper(II) complex

Authors
Gyepes, E Glowiak, T Miklos, D
Citation
E. Gyepes et al., Redetermination of the structure of bis[chloro-2-(2-hydroxy-4,5-dimethylphenylazo)-5, 5-dimethyl-4,5,6,7-tetrahydrobenzothiazol-7-on] copper(II) complex, J CHEM CRYS, 30(8), 2000, pp. 505-507
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
30
Issue
8
Year of publication
2000
Pages
505 - 507
Database
ISI
SICI code
1074-1542(200008)30:8<505:ROTSOB>2.0.ZU;2-Y
Abstract
The crystal structure Of C17H18ClCuN3O2S (M = 854.78, monoclinic, P2(1)/c, a = 8.316(2), b = 18.461(4), c = 11.774(2) Angstrom, beta = 99.64(3)degrees , V = 1782.0(7) Angstrom (3), Z = 4) is formed by dimeric Molecules [C17H18 ClCuN3O2S](2) with two monomeric units linked together by two chlorine atom s. The Cu atom is coordinated by two chlorine atoms, an oxygen atom, the az o nitrogen atom attached to the benzene ring, and the nitrogen atom of the thiazole ring, in the form of a distorted tetragonal pyramid.