Crystal structure of [Yb(L(NO3)(2)(H2O)(2)](NO3),L = bromo-N,N,N ',N '-tetraethylmalonamide

Authors
Drew, MGB Hudson, MJ Iveson, PB Madic, C
Citation
Mgb. Drew et al., Crystal structure of [Yb(L(NO3)(2)(H2O)(2)](NO3),L = bromo-N,N,N ',N '-tetraethylmalonamide, J CHEM CRYS, 30(7), 2000, pp. 455-458
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
30
Issue
7
Year of publication
2000
Pages
455 - 458
Database
ISI
SICI code
1074-1542(200007)30:7<455:CSO[=B>2.0.ZU;2-T
Abstract
[Yb(L(NO3)(2)(H2O)(2)](NO3), L = Bromo-N,N,N ' ,N ' -tetraethylmalonamide c rystallizes in the triclinic spacegroup P-1 with cell dimensions a = 9.030( 9), b = 12.036(12), c = 12.392(13) Angstrom, alpha = 84.52(1), beta = 77.58 (1), gamma = 67.21(1)degrees, d(calc) = 1.935 g cm(-3) for Z = 2. The ytter bium atom in the complex cation is nine-coordinate being bonded to two oxyg en atoms from the malonamide ligand, two nitrate anions, and three water mo lecules.